Instrumentation
550MHz Solid-state NMR Spectrometer
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The 500 MHz spectrometer utilizes
a Magnex 89mm bore super conducting
magnet fitted with room temperature shims and a homebuilt controller
designed to compensate for magnetic drift. The spectrometer
is based on a commercially available Tecmag Apollo console
that includes the pulse programmer, RF, and digitizer; all controlled by a Dell PC computer. Three channels are
available with 500 MHz amplification accomplished by a solid
state first stage and tuned tube amplifier final stage. The
X and Y RF channels of the three channel Apollo system
utilize an ENI and AMT amplifier respectively. This spectrometer is outfitted with a home built transmit and
receive circuit employing a Miteq preamplifier, and uses
semi-rigid coaxial quarter waves and diodes optimized for
experiments routinely performed in the laboratory. Variable
temperature NMR operation is achieved with the use of a
Haake F3 variable temperature bath and a home-built
controller that regulates the probes' internal heater.
Several home-built probes are available for this system
including double resonance 15N, 1H in both flat and round
coil configurations, a 2H, 1H double resonance round coil
probe and 1H, 15N and 13C triple resonance probes, all
capable of our typical variable temperature operation. |